Monday, Dec 21, 2020 at 23:23
I suppose it's possible that a rotating tyre under pressure and load *might* stay more supple than a long-term stored tyre but I very much doubt that oxidation can be "pumped" out of a tyre as he claims Cuppa.
No idea if it has credibility but fwiw I just found this.
The Science of Tire Aging
Extract follows, the "Usage" bit apparently confirming Uniroyal's claim.
The Science of Aging
“Tires are primarily degrading from the inside-out, due [to] permeation and reaction of the pressurized oxygen within the tire structure, with rates proportional to temperature.” - Summary of NHTSA Tire Aging
Test Development Research
Tire aging is an issue of oxidation. As rubber is exposed to oxygen, it dries out and becomes stiffer, leading to cracking. The issue is primarily about how the inner, “wedge” layers of rubber oxidize.
The stiffening and cracking of aged rubber can lead to the inner layers of the tire delaminating from the steel belts rather than flexing with the steel as the tire rolls underweight.
There are essentially four major factors that determine how fast a tire will age:
The Inner Liner:
The inner liner of any tire is a specialized butyl rubber compound that is designed to be impermeable to air to keep the air inside the tire where it belongs. No inner liner is entirely waterproof, so some air will always leak slowly through the liner due to osmosis. The quality of the inner liner determines just how much air leaks through, and therefore how fast the inner structure of the tire is exposed to oxygen.
Oxygen Concentration:
It's pretty easy to see that oxidation rates will increase when the oxygen concentration is higher. What this means is that a tire that is mounted and filled with compressed air will age much faster than a tire that is just being stored, because the air pressure is orders of magnitude higher in a filled tire, and more oxygen will permeate through the liner.
Heat:
Oxidation of rubber occurs much faster under high heat than low heat. In essence, heat increases both the permeability and reactivity of oxygen, making it both easier for oxygen to get through the inner liner and easier for it to react with the rubber inside the tire.
Usage:
When a tire is driven, the pressure and flexing motion circulate the internal oils through the rubber. These oils lubricate the internal rubber and keep it from drying and stiffening. So tires that are used less are often more vulnerable to aging effects.
There are quite a few scientific papers on "rubber" degradation but those I found required a subscription. Suffice to say that newer is (ought to be) significantly better than older, but that's common knowledge.
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