Wednesday, Oct 24, 2018 at 12:30
RMD - "in what way is Toyota metallurgy any different to any other engines?"
In the iron, alumimium, and magnesium alloys they utilise, as
well as the range of thermoplastics, rubber and gasket and seal materials.
The range of new alloys in use in modern engines, is ever-increasing. Toyota are at the forefront of the newest metallurgy techniques, as regards engine alloys - from the basic iron alloys, right through to magnesium and aluminium alloys, that now contain a staggering array of additives.
Toyota use aluminium and magnesium alloys that contain varying levels of iron, copper, zirconium, silicon, manganese, nickel, zinc, and even ceramics and strengthening fibres such as silicon carbide and alumina-boria.
Varying alloying elements added to to the light alloys, affect the corrosion resistance of those alloys - sometimes improving the corrosion resistance, and sometimes worsening it.
Manganese is added to aluminium and magnesium alloys to improve corrosion protection. Magnesium suffers the worst from galvanic corrosion (dissimilar metals reaction corrosion).
Coolants have to be compatible with iron components, aluminium radiators and heater cores, alloy blocks and heads, magnesium-alloy engine components, gaskets and seals of varying material construction, thermoplastics used in piping, thermostat housings and radiator tanks, and a multitude of hoses and piping.
Toyota Long-Life coolant contains 934ml/L ethylene glycol plus a range of corrosion-controlling additives known as OAT's (Organic Acid Technology).
Those OAT's are proprietary (commercially secret) to Toyota, but are known to be sebacate, plus silicates, plus phosphate compounds, plus other proprietary protective ingredients, in small amounts.
The latest Toyota coolant is known as a H-OAT (Hybrid Organic Acid Technology - because it has phosphates added, and silicates reduced or eliminated).
The phosphate compounds in Toyota coolant generate a rapid coating on exposed aluminium and magnesium components, which can become exposed to air, when air enters the cooling system.
Light alloy components in engines and cooling systems can rapidly corrode when exposed to air at high temperatures, such as those found in hot engines.
There was a legal kerfuffle in the U.S. when an additive known as 2-EHA (2-ethylhexanoic acid) in Dex-Cool coolant, was found to be a plasticiser (a product that softens plastics and rubber).
Toyota coolant does not contain 2-EHA and as such, there is no possibility of plastics or rubber softening in engine components, when using it.
Toyota do extensive, long-term testing on their specific engine metallurgy, and many of the ingredients in those Toyota metals (and plastics) are known only to them, due to proprietary design and engineering.
For any company making aftermarket coolants, they would have to know the precise levels of each additive to Toyota metals and alloys, and the precise composition of every component in Toyotas engines, that is in contact with hot coolant.
I don't believe that is possible, and I believe that all aftermarket coolant manufacturers merely use a basic ethylene glycol content in their coolants, and throw in a few known additives - on the basis of a "one-size-fits-all" approach - and that they believe this then provides adequate cooling system and engine component protection on a general basis.
However, generalising in this manner, when each manufacturer uses different, and often company-specific alloys and metallurgy, is highly unsatisfactory, in my view.
I have personal experience of using "alternative" coolants in Toyotas, with resultant cooling system corrosion issues.
All of the above is just my .02c worth, based on over 50 years of very extensive ownership and experience of a substantial range of engines, equipment, machines and vehicles, and long experience with a wide range of corrosion issues in cooling systems.
My experience goes right back to early days of soluble oil being the only cooling system additive to prevent corrosion. My, how things have changed.
Cheers, Ron.
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